{"id":69,"date":"2021-01-11T11:29:47","date_gmt":"2021-01-11T11:29:47","guid":{"rendered":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/2021\/01\/11\/analytical-measurements-can-predict-organic-solar-cell-stability\/"},"modified":"2026-06-08T19:06:48","modified_gmt":"2026-06-08T23:06:48","slug":"analytical-measurements-can-predict-organic-solar-cell-stability","status":"publish","type":"post","link":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/2021\/01\/11\/analytical-measurements-can-predict-organic-solar-cell-stability\/","title":{"rendered":"Analytical Measurements Can Predict Organic Solar Cell Stability"},"content":{"rendered":"\n

For Immediate Release<\/h2>\n
Tracey Peake<\/span>tracey_peake@ncsu.edu<\/a><\/div>\n<\/section>\n\n\n\n

North Carolina State University-led researchers have developed an analytical measurement \u201cframework\u201d which could allow organic solar cell researchers and manufacturers to determine which materials will produce the most stable solar cells prior to manufacture.<\/p>\n\n\n\n

Organic solar cells have increased in efficiency over the past decades, but researchers and manufacturers still struggle with determining which material combinations work best and why, as well as with achieving stable morphology and operation.<\/p>\n\n\n\n

\u201cThere is still a lot of \u2018trial and error\u2019 guesswork involved in identifying promising materials for these solar cells,\u201d says Harald Ade, Goodnight Innovation Distinguished Professor of Physics at NC State and co-corresponding author of the research. \u201cHowever, we found that if you understand two important parameters for the materials being used, you can predict how stable the active layer morphology will be, which in turn affects efficiency over time.\u201d<\/p>\n\n\n\n

The parameters in question are the elastic modulus and glass transition \u2013 essentially how stiff the material is and at what temperature the material transitions from a rigid state to a rubbery or viscous fluid state.<\/p>\n\n\n\n

\u201cThe most efficient solar cells are composed of a blend of materials that typically have poor miscibility,\u201d says Brendan O\u2019Connor, associate professor of mechanical and aerospace engineering at NC State and co-corresponding author of the research. \u201cIdeally, these blends need to be mixed during fabrication to an optimized composition, but over time they can separate or diffuse into domains that are too pure, which leads to device degradation.<\/p>\n\n\n\n

\u201cWe wanted to understand what drives this instability in composition. We found that the molecular interactions that fundamentally drive diffusion behavior could be captured with the \u2018proxy-parameters\u2019 of elastic modulus and glass transition temperature.\u201d<\/p>\n\n\n\n

The team, led by NC State postdoctoral researcher Masoud Ghasemi, used secondary ion mass spectrometry (SIMS), to measure the diffusion behavior of small molecules into a pure polymer layer. They also used differential scanning calorimetry (DSC), and a wrinkling metrology approach to measure the glass transition and elastic modulus of a number of materials that are commonly used in organic solar cells.<\/p>\n\n\n\n

Overall, the team found that the most stable organic solar cells contained a small molecule with a high glass transition temperature and a polymer with a large elastic modulus; in other words, a highly rigid material.<\/p>\n\n\n\n

\u201cThe more rigid materials also have the lowest inherent miscibility,\u201d Ghasemi says. \u201cInterestingly, this means that the materials that do not like to mix have the lowest diffusion when forced to do so, resulting in the most stable solar cells.\u201d<\/p>\n\n\n\n

\u201cOur findings are fairly intuitive,\u201d Ade says, \u201cbut finding that there is a quantitative relationship between elastic modulus, glass transition and the molecular interactions inside these materials allows us to capture interaction forces at a local level, predicting stability in these systems without requiring trial and error.\u201d<\/p>\n\n\n\n

The research appears in Nature Materials<\/a> and was supported in part by the Office of Naval Research and the National Science Foundation. Researchers from the University of North Carolina at Chapel Hill, the University of Kentucky, Imperial College London and the University of Oxford, U.K., also contributed to the work.<\/p>\n\n\n\n

-peake-<\/p>\n\n\n\n

Note to editors:<\/strong> An abstract follows.<\/p>\n\n\n\n

\u201cA molecular interaction\u2013diffusion framework for predicting organic solar cell stability\u201d<\/strong><\/p>\n\n\n\n

DOI: 10.1038\/s41563-020-00872-6<\/a><\/strong><\/p>\n\n\n\n

Authors<\/em>: Masoud Ghasemi, Nrup Balar, Zhengxing Peng, Huawei Hu, Yunpeng Qin, Taesoo Kim, Aram Amassian, Brendan T. O\u2019Connor and Harald Ade, North Carolina State University; Jeromy James Rech, Wei You, University of North Carolina at Chapel Hill; Matthew Bidwell, Imperial College, London; Walter Mask, Chad Risko, University of Kentucky; Iain McCulloch, University of Oxford, U.K.
Published<\/em>: Online in Nature Materials<\/em><\/p>\n\n\n\n

Abstract:<\/strong>
Rapid increase in the power conversion efficiency of organic solar cells (OSCs) has been achieved with the development of non-fullerene-small molecule acceptors (NF-SMAs). Although the morphological stability of these NF-SMA devices critically affects their intrinsic lifetime, their fundamental intermolecular interactions and how they govern property\u2013function relations and morphological stability of OSCs remain elusive. Here, we discover that the diffusion of an NF-SMA into the donor polymer exhibits Arrhenius behaviour and that the activation energy Ea scales linearly with the enthalpic interaction parameters \u03c7H between the polymer and the NF-SMA. Consequently, the thermodynamically most unstable, hypo-miscible systems (high \u03c7) are the most kinetically stabilized. We relate the differences in Ea to measured and selectively simulated molecular self-interaction properties of the constituent materials and develop quantitative property\u2013function relations that link thermal and mechanical characteristics of the NF-SMA and polymer to predict relative diffusion properties and thus morphological stability.<\/p>\n

This post was originally published<\/a> in NC State News.<\/em><\/p>","protected":false,"raw":"\n\n\n\n\n

For Immediate Release<\/h2>\n
Tracey Peake<\/span>tracey_peake@ncsu.edu<\/a><\/div>\n<\/section>\n\n\n\n

North Carolina State University-led researchers have developed an analytical measurement \u201cframework\u201d which could allow organic solar cell researchers and manufacturers to determine which materials will produce the most stable solar cells prior to manufacture.<\/p>\n\n\n\n

Organic solar cells have increased in efficiency over the past decades, but researchers and manufacturers still struggle with determining which material combinations work best and why, as well as with achieving stable morphology and operation.<\/p>\n\n\n\n

\u201cThere is still a lot of \u2018trial and error\u2019 guesswork involved in identifying promising materials for these solar cells,\u201d says Harald Ade, Goodnight Innovation Distinguished Professor of Physics at NC State and co-corresponding author of the research. \u201cHowever, we found that if you understand two important parameters for the materials being used, you can predict how stable the active layer morphology will be, which in turn affects efficiency over time.\u201d<\/p>\n\n\n\n

The parameters in question are the elastic modulus and glass transition \u2013 essentially how stiff the material is and at what temperature the material transitions from a rigid state to a rubbery or viscous fluid state.<\/p>\n\n\n\n

\u201cThe most efficient solar cells are composed of a blend of materials that typically have poor miscibility,\u201d says Brendan O\u2019Connor, associate professor of mechanical and aerospace engineering at NC State and co-corresponding author of the research. \u201cIdeally, these blends need to be mixed during fabrication to an optimized composition, but over time they can separate or diffuse into domains that are too pure, which leads to device degradation.<\/p>\n\n\n\n

\u201cWe wanted to understand what drives this instability in composition. We found that the molecular interactions that fundamentally drive diffusion behavior could be captured with the \u2018proxy-parameters\u2019 of elastic modulus and glass transition temperature.\u201d<\/p>\n\n\n\n

The team, led by NC State postdoctoral researcher Masoud Ghasemi, used secondary ion mass spectrometry (SIMS), to measure the diffusion behavior of small molecules into a pure polymer layer. They also used differential scanning calorimetry (DSC), and a wrinkling metrology approach to measure the glass transition and elastic modulus of a number of materials that are commonly used in organic solar cells.<\/p>\n\n\n\n

Overall, the team found that the most stable organic solar cells contained a small molecule with a high glass transition temperature and a polymer with a large elastic modulus; in other words, a highly rigid material.<\/p>\n\n\n\n

\u201cThe more rigid materials also have the lowest inherent miscibility,\u201d Ghasemi says. \u201cInterestingly, this means that the materials that do not like to mix have the lowest diffusion when forced to do so, resulting in the most stable solar cells.\u201d<\/p>\n\n\n\n

\u201cOur findings are fairly intuitive,\u201d Ade says, \u201cbut finding that there is a quantitative relationship between elastic modulus, glass transition and the molecular interactions inside these materials allows us to capture interaction forces at a local level, predicting stability in these systems without requiring trial and error.\u201d<\/p>\n\n\n\n

The research appears in Nature Materials<\/a> and was supported in part by the Office of Naval Research and the National Science Foundation. Researchers from the University of North Carolina at Chapel Hill, the University of Kentucky, Imperial College London and the University of Oxford, U.K., also contributed to the work.<\/p>\n\n\n\n

-peake-<\/p>\n\n\n\n

Note to editors:<\/strong> An abstract follows.<\/p>\n\n\n\n

\u201cA molecular interaction\u2013diffusion framework for predicting organic solar cell stability\u201d<\/strong><\/p>\n\n\n\n

DOI: 10.1038\/s41563-020-00872-6<\/a><\/strong><\/p>\n\n\n\n

Authors<\/em>: Masoud Ghasemi, Nrup Balar, Zhengxing Peng, Huawei Hu, Yunpeng Qin, Taesoo Kim, Aram Amassian, Brendan T. O\u2019Connor and Harald Ade, North Carolina State University; Jeromy James Rech, Wei You, University of North Carolina at Chapel Hill; Matthew Bidwell, Imperial College, London; Walter Mask, Chad Risko, University of Kentucky; Iain McCulloch, University of Oxford, U.K.
Published<\/em>: Online in Nature Materials<\/em><\/p>\n\n\n\n

Abstract:<\/strong>
Rapid increase in the power conversion efficiency of organic solar cells (OSCs) has been achieved with the development of non-fullerene-small molecule acceptors (NF-SMAs). Although the morphological stability of these NF-SMA devices critically affects their intrinsic lifetime, their fundamental intermolecular interactions and how they govern property\u2013function relations and morphological stability of OSCs remain elusive. Here, we discover that the diffusion of an NF-SMA into the donor polymer exhibits Arrhenius behaviour and that the activation energy Ea scales linearly with the enthalpic interaction parameters \u03c7H between the polymer and the NF-SMA. Consequently, the thermodynamically most unstable, hypo-miscible systems (high \u03c7) are the most kinetically stabilized. We relate the differences in Ea to measured and selectively simulated molecular self-interaction properties of the constituent materials and develop quantitative property\u2013function relations that link thermal and mechanical characteristics of the NF-SMA and polymer to predict relative diffusion properties and thus morphological stability.<\/p>\n"},"excerpt":{"rendered":"

An analytical measurement framework could help organic solar cell manufacturers determine the best materials for stable solar cells.<\/p>\n","protected":false},"author":4,"featured_media":70,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"source":"ncstate_wire","ncst_dynamicHeaderBlockName":"","ncst_dynamicHeaderData":"","ncst_content_audit_freq":"","ncst_content_audit_date":"","ncst_content_audit_display":false,"ncst_backToTopFlag":"","footnotes":""},"categories":[6,1],"tags":[5],"class_list":["post-69","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research","category-uncategorized","tag-_from-newswire-collection-6"],"displayCategory":null,"acf":[],"_links":{"self":[{"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/posts\/69","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/comments?post=69"}],"version-history":[{"count":3,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/posts\/69\/revisions"}],"predecessor-version":[{"id":2275,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/posts\/69\/revisions\/2275"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/media\/70"}],"wp:attachment":[{"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/media?parent=69"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/categories?post=69"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/dev.ucomm.ncsu.edu\/web-platform-free-tier\/wp-json\/wp\/v2\/tags?post=69"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}